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세션명 분자전자 부문위원회 (II)
발표장 제1회장
논문코드 2L1-5
발표일 2021-10-22
발표시간 14:50-15:15
논문제목 Chemistry of Ionic Endohedral Fullerenes
발표자 Hiroshi UENO
발표자 소속 Tohoku University
저자 Hiroshi UENO
소속 Tohoku University
논문초록 Inserting a small chemical species into fullerenes is a fascinating method to endow them with unique characteristic properties. Previously, a powerful method to access alkali metal encapsulated fullerenes, so-called “plasma implantation”, has been developed, which enabled us to achieve scalable synthesis of Li+-encapsulated fullerenes. These compounds are regarded as an “ion-encapsulated fullerene” which is a new fullerene family, but should not be categorized into general endohedral metallofullerenes. As a result of significant progress in the basic studies during the past 10 years, the characteristic properties arising from the ionic natures have been successively explored. I present here the outline of our studies on ion-encapsulated fullerenes including synthetic approach, basic properties, reactivity, and application for perovskite solar cell, aiming at triggering the broad and interdisciplinary expansion of the novel materials.